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- W2950536461 abstract "Some new fluorine-containing enynic esters, enynylphosphine oxides, and enynylphosphates were synthesized stereoselectively in good yields by the dehydrohalogenation reaction of fluoroalkylated 3-iodoacrylates, 2-iodovinylphosphonates, and 2-iodovinylphosphine oxides under basic conditions. These fluorine-containing enynic compounds could undergo carbocupration reaction with organocopper reagents and the vinylcopper intermediates formed in situ could further react with some electrophiles such as allyl bromide, phenylselenyl bromide, and iodine to give the corresponding polysubstituted fluorine-containing dienoic esters, phosphates, and phosphine oxides with high regio- and stereoselectivity." @default.
- W2950536461 created "2019-06-27" @default.
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- W2950536461 date "2008-09-01" @default.
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- W2950536461 title "Synthesis and selective carbocupration reaction of fluorine-containing enynic esters, enynylphosphine oxides, and enynylphosphates" @default.
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- W2950536461 doi "https://doi.org/10.1016/j.tet.2008.06.084" @default.
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