Matches in SemOpenAlex for { <https://semopenalex.org/work/W2950548894> ?p ?o ?g. }
Showing items 1 to 86 of
86
with 100 items per page.
- W2950548894 endingPage "2835" @default.
- W2950548894 startingPage "2830" @default.
- W2950548894 abstract "A new open-framework manganese−gallium phosphate has been synthesized under solvothermal conditions and characterized by single-crystal XRD, thermogravimetric analysis, and magnetic susceptibility measurements [crystal data: [MnGa(PO3OH)2(PO4)][C6N2H14], Mr = 525.76, monoclinic, space group P21/n (No. 14), a = 10.193(1), b = 14.276(1), and c = 10.380 (1) Å, β = 91.184(8)°, V = 1510 Å3, Z = 4, R = 5.8%, Rw = 7.8% (2331 observed data with I > 3σ(I))]. The structure consists of MnO5, GaO4, and PO4 units linked to form a three-dimensional microporous framework encapsulating 1,4-diazabicyclo[2.2.2]octane cations. The Mn2+ ions have distorted square-pyramidal geometry and exist in Mn2(HPO4)4 units within the framework. Antiferromagnetic ordering at TN = 10(1) K is ascribed to coupling between Mn2+ ions in these subunits, and the temperature dependence of the susceptibility can be successfully fitted assuming a Heisenberg exchange interaction (J = −2.07(1) cm-1, g = 2.25(1)). At higher temperatures (>70 K) Curie−Weiss paramagnetism is observed (θ = −20.2(2) K, μeff = 6.69(1)μB)." @default.
- W2950548894 created "2019-06-27" @default.
- W2950548894 creator A5059951679 @default.
- W2950548894 creator A5087286871 @default.
- W2950548894 creator A5091230017 @default.
- W2950548894 creator A5091639431 @default.
- W2950548894 date "1997-12-01" @default.
- W2950548894 modified "2023-10-16" @default.
- W2950548894 title "MnGaPO-2: Synthesis and Characterization of [MnGa(PO<sub>3</sub>OH)<sub>2</sub>(PO<sub>4</sub>)][C<sub>6</sub>N<sub>2</sub>H<sub>14</sub>], a New Microporous Manganese−Gallium Phosphate" @default.
- W2950548894 cites W1974089223 @default.
- W2950548894 cites W1982834674 @default.
- W2950548894 cites W2013483518 @default.
- W2950548894 cites W2025157535 @default.
- W2950548894 cites W2033112456 @default.
- W2950548894 cites W2053337147 @default.
- W2950548894 cites W2053612465 @default.
- W2950548894 cites W2054141639 @default.
- W2950548894 cites W2059401704 @default.
- W2950548894 cites W2091523369 @default.
- W2950548894 cites W2096375277 @default.
- W2950548894 cites W2101741054 @default.
- W2950548894 cites W2124015677 @default.
- W2950548894 cites W2130697583 @default.
- W2950548894 cites W2135098829 @default.
- W2950548894 cites W2161698130 @default.
- W2950548894 cites W2218083856 @default.
- W2950548894 doi "https://doi.org/10.1021/cm9701623" @default.
- W2950548894 hasPublicationYear "1997" @default.
- W2950548894 type Work @default.
- W2950548894 sameAs 2950548894 @default.
- W2950548894 citedByCount "27" @default.
- W2950548894 countsByYear W29505488942014 @default.
- W2950548894 crossrefType "journal-article" @default.
- W2950548894 hasAuthorship W2950548894A5059951679 @default.
- W2950548894 hasAuthorship W2950548894A5087286871 @default.
- W2950548894 hasAuthorship W2950548894A5091230017 @default.
- W2950548894 hasAuthorship W2950548894A5091639431 @default.
- W2950548894 hasConcept C115624301 @default.
- W2950548894 hasConcept C121332964 @default.
- W2950548894 hasConcept C124712363 @default.
- W2950548894 hasConcept C145148216 @default.
- W2950548894 hasConcept C155355069 @default.
- W2950548894 hasConcept C16889073 @default.
- W2950548894 hasConcept C178790620 @default.
- W2950548894 hasConcept C185592680 @default.
- W2950548894 hasConcept C191897082 @default.
- W2950548894 hasConcept C192562407 @default.
- W2950548894 hasConcept C26873012 @default.
- W2950548894 hasConcept C528890316 @default.
- W2950548894 hasConcept C61276311 @default.
- W2950548894 hasConcept C8010536 @default.
- W2950548894 hasConceptScore W2950548894C115624301 @default.
- W2950548894 hasConceptScore W2950548894C121332964 @default.
- W2950548894 hasConceptScore W2950548894C124712363 @default.
- W2950548894 hasConceptScore W2950548894C145148216 @default.
- W2950548894 hasConceptScore W2950548894C155355069 @default.
- W2950548894 hasConceptScore W2950548894C16889073 @default.
- W2950548894 hasConceptScore W2950548894C178790620 @default.
- W2950548894 hasConceptScore W2950548894C185592680 @default.
- W2950548894 hasConceptScore W2950548894C191897082 @default.
- W2950548894 hasConceptScore W2950548894C192562407 @default.
- W2950548894 hasConceptScore W2950548894C26873012 @default.
- W2950548894 hasConceptScore W2950548894C528890316 @default.
- W2950548894 hasConceptScore W2950548894C61276311 @default.
- W2950548894 hasConceptScore W2950548894C8010536 @default.
- W2950548894 hasIssue "12" @default.
- W2950548894 hasLocation W29505488941 @default.
- W2950548894 hasOpenAccess W2950548894 @default.
- W2950548894 hasPrimaryLocation W29505488941 @default.
- W2950548894 hasRelatedWork W1979358532 @default.
- W2950548894 hasRelatedWork W1998942951 @default.
- W2950548894 hasRelatedWork W2049564750 @default.
- W2950548894 hasRelatedWork W2081595343 @default.
- W2950548894 hasRelatedWork W2082823139 @default.
- W2950548894 hasRelatedWork W216922106 @default.
- W2950548894 hasRelatedWork W2314729056 @default.
- W2950548894 hasRelatedWork W2315457165 @default.
- W2950548894 hasRelatedWork W2957954 @default.
- W2950548894 hasRelatedWork W3144435710 @default.
- W2950548894 hasVolume "9" @default.
- W2950548894 isParatext "false" @default.
- W2950548894 isRetracted "false" @default.
- W2950548894 magId "2950548894" @default.
- W2950548894 workType "article" @default.