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- W2950549557 abstract "Because there are no general reaction conditions for any glycosylation method, biologically interesting oligosaccharides can only be made in a small number of laboratories in the world. To make carbohydrate synthesis accessible to nonspecialists, it is critical to have glycosylation methods that will work in a wide range of cases under a single set of conditions. The Lewis blood group antigens have attracted the attention of numerous synthetic carbohydrate groups because of their structural complexity. Although they have been synthesized many times, they have never been made using a single glycosylation method under one set of reaction conditions. In this paper, we show that the sulfoxide glycosylation method can be used to form all of the glycosidic linkages in the Lewis blood group antigens Lea (1), Leb (2), and Lex (3) stereoselectively under a uniform set of reaction conditions. This work highlights the flexibility of the sulfoxide method and demonstrates its utility for constructing families of relat..." @default.
- W2950549557 created "2019-06-27" @default.
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- W2950549557 date "2010-08-25" @default.
- W2950549557 modified "2023-09-26" @default.
- W2950549557 title "ChemInform Abstract: Generalizing Glycosylation: Synthesis of the Blood Group Antigens Lea, Leb, and Lex Using a Standard Set of Reaction Conditions." @default.
- W2950549557 cites W2016089257 @default.
- W2950549557 doi "https://doi.org/10.1002/chin.199703262" @default.
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