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• W2950551946 abstract "A three-step sequence to prepare polycyclic 2,5-dihydropyrroles from alpha-silyloxy ketones is presented. A Lewis acid-mediated ring fragmentation of cyclic gamma-silyloxy-beta-hydroxy-alpha-diazo esters provided tethered aldehyde ynoate intermediates which, when treated with amino acid silyl esters, underwent intramolecular azomethine ylide 1,3-dipolar cycloadditions. The 2,5-dihydropyrrole products were formed in good to excellent yield as single diastereomers." @default.
• W2950551946 created "2019-06-27" @default.
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• W2950551946 date "2009-10-14" @default.
• W2950551946 modified "2023-10-01" @default.
• W2950551946 title "An Efficient Synthetic Approach to Polycyclic 2,5-Dihydropyrroles from α-Silyloxy Ketones" @default.
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• W2950551946 doi "https://doi.org/10.1021/jo901978y" @default.
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