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- W2950551982 abstract "The interaction of Me3SiOTf and (C6F5)3SiOTf with enamines generating α-silyl-substituted iminium ions is investigated. A trimethylsilyl iminium cation is formed as a long-lived species observable by NMR spectroscopy, whilst the tris(pentafluorophenyl)silyl analogue is very labile and prone to the loss of a proton. On the basis of the latter phenomenon, a method for the synthesis of β-silyl enamines is proposed." @default.
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- W2950551982 date "2005-05-01" @default.
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- W2950551982 title "On the interaction of silyl triflates with enamines: iminium ion formation versus silylation" @default.
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- W2950551982 doi "https://doi.org/10.1016/j.tetlet.2005.03.144" @default.
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