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• W2950552848 endingPage "7850" @default.
• W2950552848 startingPage "7844" @default.
• W2950552848 abstract "The solid-state syntheses, crystal structures, and characterization of two stoichiometrically similar quaternary mixed metal selenite and tellurite, In2Zn(SeO3)4 and Ga2Zn(TeO3)4, respectively, are reported. While In2Zn(SeO3)4 crystallizes in the centrosymmetric monoclinic space group P21/n (No. 14) with a = 8.4331(7) Å, b = 4.7819(4) Å, c = 14.6583(13) Å, and β = 101.684(6)°, Ga2Zn(TeO3)4 crystallizes in the non-centrosymmetric space group I-43d (No. 220) with a = b = c = 10.5794(8) Å. In2Zn(SeO3)4 exhibits a two-dimensional crystal structure consisting of distorted InO6 octahedra, ZnO6 octahedra, and SeO3 polyhedra. Ga2Zn(TeO3)4 shows a three-dimensional framework structure that is composed of GaO4 or ZnO4 and TeO3 polyhedra. An effect of the framework flexibility on the space group centricity is discussed. The SHG (second harmonic generation) efficiency of noncentrosymmetric Ga2Zn(TeO3)4, using 1064 nm radiation, is similar to that of KH2PO4 (KDP) and is not phase-matchable (Type 1). Complete characterizations including infrared spectroscopy and thermal analyses for the reported materials are also presented, as are dipole moment calculations." @default.
• W2950552848 created "2019-06-27" @default.
• W2950552848 creator A5024769260 @default.
• W2950552848 creator A5034337633 @default.
• W2950552848 creator A5054799694 @default.
• W2950552848 creator A5073923034 @default.
• W2950552848 creator A5091554389 @default.
• W2950552848 date "2012-07-02" @default.
• W2950552848 modified "2023-09-27" @default.
• W2950552848 title "Effect of the Framework Flexibility on the Centricities in Centrosymmetric In₂Zn(SeO₃)₄ and Noncentrosymmetric Ga₂Zn(TeO₃)₄" @default.
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• W2950552848 doi "https://doi.org/10.1021/ic300909s" @default.
• W2950552848 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/22793171" @default.
• W2950552848 hasPublicationYear "2012" @default.
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