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- W2950553016 abstract "A novel one-step procedure for the synthesis of 2-substituted-isoindoles and 1-aryl-2-substituted-isoindoles is described. The procedure is based on the reaction of 2-(bromomethyl)benzaldehyde or 2-(bromomethyl)benzophen-one derivatives with primary aromatic or aliphatic amines. Reactions of 1,2-diarylisoindoles with N-phenylmaleimide were studied. Refluxing the reactants in i-PrOH in the presence of triethylamine leads to the formation of Diels–Alder endo-adducts; whilst refluxing in AcOH in the presence of AcONa affords Michael adducts. The structure of the latter was confirmed by X-ray diffraction." @default.
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- W2950553016 date "2011-11-01" @default.
- W2950553016 modified "2023-09-25" @default.
- W2950553016 title "2-Substituted-Isoindoles: A Novel Synthetic Route and a Study of the Diels–Alder and Michael Reactions" @default.
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- W2950553016 doi "https://doi.org/10.3184/174751911x13179842027190" @default.
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