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- W2950553554 abstract "The molecular structure of SbI3 and BiI3 have been studied by gas-phase electron diffraction and infrared spectroscopy, BiI3 has been studied by electron diffraction, and SbI3 has been studied by infrared spectroscopy for the first time. Both molecules are pyramidal (C3v symmetry), and their geometries are characterized by the following bond lengths (rg) and bond angles (∠α): Sb−I 2.721 ± 0.005 Å, I−Sb−I 99.0 ± 0.3°, Bi−I 2.807 ± 0.006 Å, and I−Bi−I 99.5 ± 0.3°. Three of the four normal modes of vibration were observed for both molecules: SbI3, ν2 = 74.4 cm-1, ν3 = 193.6 cm-1, and ν4 = 54.6 cm-1; BiI3, ν2 = 59.7 cm-1, ν3 = 163.5 cm-1, and ν4 = 47.0 cm-1. A joint electron diffraction/vibrational spectroscopic analysis was also carried out, from which the harmonic equilibrium geometries were estimated. Force field parameters from a normal coordinate analysis are reported for both molecules." @default.
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- W2950553554 date "1996-01-01" @default.
- W2950553554 modified "2023-10-14" @default.
- W2950553554 title "Molecular Structure of SbI<sub>3</sub> and BiI<sub>3</sub> from Combined Electron Diffraction and Vibrational Spectroscopic Studies" @default.
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- W2950553554 doi "https://doi.org/10.1021/ic960601k" @default.
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