Matches in SemOpenAlex for { <https://semopenalex.org/work/W2950554751> ?p ?o ?g. }
Showing items 1 to 71 of
71
with 100 items per page.
- W2950554751 abstract "Consequences of proton-transfer reactions in guanidine in the solid state, solution and gas phase are discussed. Y-delocalization, resonance and symmetry strongly influence the basicity of guanidine in the gas phase. These effects are, however, insufficient to explain the basicity of guanidine which in aqueous solution is stronger than that of trisubstituted alkylamines and proton sponge (DMAN). The intrinsic (gas-phase) basicity of guanidine is close to that of triethylamine. The large difference between the basicities of amines and guanidine in solution is attributed to the important role played by effects such as polarizability and internal and external solvation. Copyright © 2003 John Wiley & Sons, Ltd." @default.
- W2950554751 created "2019-06-27" @default.
- W2950554751 creator A5003180390 @default.
- W2950554751 creator A5033748917 @default.
- W2950554751 creator A5040577451 @default.
- W2950554751 creator A5043274569 @default.
- W2950554751 creator A5046850140 @default.
- W2950554751 creator A5051015373 @default.
- W2950554751 creator A5066003255 @default.
- W2950554751 creator A5077254027 @default.
- W2950554751 date "2003-07-22" @default.
- W2950554751 modified "2023-10-13" @default.
- W2950554751 title "Consequences of Proton Transfer in Guanidine" @default.
- W2950554751 cites W2083954238 @default.
- W2950554751 doi "https://doi.org/10.1002/chin.200329269" @default.
- W2950554751 hasPublicationYear "2003" @default.
- W2950554751 type Work @default.
- W2950554751 sameAs 2950554751 @default.
- W2950554751 citedByCount "0" @default.
- W2950554751 crossrefType "journal-article" @default.
- W2950554751 hasAuthorship W2950554751A5003180390 @default.
- W2950554751 hasAuthorship W2950554751A5033748917 @default.
- W2950554751 hasAuthorship W2950554751A5040577451 @default.
- W2950554751 hasAuthorship W2950554751A5043274569 @default.
- W2950554751 hasAuthorship W2950554751A5046850140 @default.
- W2950554751 hasAuthorship W2950554751A5051015373 @default.
- W2950554751 hasAuthorship W2950554751A5066003255 @default.
- W2950554751 hasAuthorship W2950554751A5077254027 @default.
- W2950554751 hasConcept C121332964 @default.
- W2950554751 hasConcept C148093993 @default.
- W2950554751 hasConcept C178790620 @default.
- W2950554751 hasConcept C185592680 @default.
- W2950554751 hasConcept C2776460385 @default.
- W2950554751 hasConcept C2779463914 @default.
- W2950554751 hasConcept C2781283055 @default.
- W2950554751 hasConcept C3020013744 @default.
- W2950554751 hasConcept C32909587 @default.
- W2950554751 hasConcept C44280652 @default.
- W2950554751 hasConcept C54516573 @default.
- W2950554751 hasConcept C62520636 @default.
- W2950554751 hasConcept C70050531 @default.
- W2950554751 hasConceptScore W2950554751C121332964 @default.
- W2950554751 hasConceptScore W2950554751C148093993 @default.
- W2950554751 hasConceptScore W2950554751C178790620 @default.
- W2950554751 hasConceptScore W2950554751C185592680 @default.
- W2950554751 hasConceptScore W2950554751C2776460385 @default.
- W2950554751 hasConceptScore W2950554751C2779463914 @default.
- W2950554751 hasConceptScore W2950554751C2781283055 @default.
- W2950554751 hasConceptScore W2950554751C3020013744 @default.
- W2950554751 hasConceptScore W2950554751C32909587 @default.
- W2950554751 hasConceptScore W2950554751C44280652 @default.
- W2950554751 hasConceptScore W2950554751C54516573 @default.
- W2950554751 hasConceptScore W2950554751C62520636 @default.
- W2950554751 hasConceptScore W2950554751C70050531 @default.
- W2950554751 hasLocation W29505547511 @default.
- W2950554751 hasOpenAccess W2950554751 @default.
- W2950554751 hasPrimaryLocation W29505547511 @default.
- W2950554751 hasRelatedWork W2025797365 @default.
- W2950554751 hasRelatedWork W2039222044 @default.
- W2950554751 hasRelatedWork W2062662558 @default.
- W2950554751 hasRelatedWork W2316275507 @default.
- W2950554751 hasRelatedWork W2341254035 @default.
- W2950554751 hasRelatedWork W2346554317 @default.
- W2950554751 hasRelatedWork W2604119016 @default.
- W2950554751 hasRelatedWork W2949090308 @default.
- W2950554751 hasRelatedWork W2951316285 @default.
- W2950554751 hasRelatedWork W2952054954 @default.
- W2950554751 isParatext "false" @default.
- W2950554751 isRetracted "false" @default.
- W2950554751 magId "2950554751" @default.
- W2950554751 workType "article" @default.