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- W2950556917 abstract "Abstract 2-Substituted-2,7,9-decatrienoates undergo an iron-catalyzed carbocyclization to yield trans -disubstituted cyclopentanes in moderate-to-good chemical yields. The cyclization products are formally the result of a [4+4]-ene reaction in which cis -propenyl and 2-acroyl functionalities are introduced as appendages to the newly formed cyclopentane ring by the cyclization. Triene ester substrates bearing an alkyl substituent at the 4- or 6-positions cyclize with high 1,2-stereoinduction to yield trisubstituted cyclopentanes in which the relative stereochemistry between three contiguous stereocenters is controlled." @default.
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- W2950556917 date "1990-12-25" @default.
- W2950556917 modified "2023-09-27" @default.
- W2950556917 title "ChemInform Abstract: Catalytic Iron-Mediated Ene Carbocyclizations: Formal (4 + 4)-Ene Reactions of Triene Esters." @default.
- W2950556917 cites W2086148981 @default.
- W2950556917 doi "https://doi.org/10.1002/chin.199052127" @default.
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