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- W2950558430 abstract "The cyanoamidation of olefins was achieved. When N-(2-vinylphenyl)cyanoformamides were treated with palladium catalyst, intramolecular cyanoamidation took place to give corresponding 3,3-disubstituted oxindoles. P(t-Bu)3 showed a remarkable effect on this reaction. When it was used with Pd(dba)2, the reaction was completed in 15 min at 100 °C for many substrates. Furthermore, the enantioselective cyanoamidation was accomplished with Pd(dba)2 and an optically active phosphoramidite to provide optically active 3,3-disubstituted oxindoles. Manipulation of the resulting oxindoles has been studied." @default.
- W2950558430 created "2019-06-27" @default.
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- W2950558430 date "2010-03-01" @default.
- W2950558430 modified "2023-09-23" @default.
- W2950558430 title "Synthesis of 3,3-disubstituted oxindoles through Pd-catalyzed intramolecular cyanoamidation" @default.
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- W2950558430 doi "https://doi.org/10.1016/j.tet.2010.01.073" @default.
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