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- W2950559239 abstract "Abstract Two stereocontrolled routes to the alkaloid depentylperhydrohistrionicotoxin 3 , are described. The key steps are alkylation, with retention of configuration, of the iodide 8 and the mesylate 12 , respectively. A tricyclic aziridinium species is proposed as the reactive intermediate in the latter reaction. The synthesis of 3 represents a formal total synthesis of the title alkaloid." @default.
- W2950559239 created "2019-06-27" @default.
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- W2950559239 date "1987-03-10" @default.
- W2950559239 modified "2023-09-24" @default.
- W2950559239 title "ChemInform Abstract: New Routes to Perhydrohistrionicotoxin." @default.
- W2950559239 cites W1981482764 @default.
- W2950559239 doi "https://doi.org/10.1002/chin.198710315" @default.
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