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- W2950562722 abstract "Treatment of 3β-hydroxyandrost-5-en-17-one with triphenylphosphine and carbon tetrachloride under various conditions affords 3α- and 3β-chloroandrost-5-en-17-one, 3α,5-cycloandrost-6-en-17-one, and minor amounts of 17-dichloromethylene derivatives. In contrast, 4β-acetoxy-3β-hydroxyandrost-5-en-17-one affords 4β-acetoxy-3α-chloro- and 3β-acetoxy-4α-chloro-androst-5-en-17-ones. 3β-Acetoxy-4β-hydroxyandrost-5-en-17-one affords 3β-acetoxyandrost-4,6-dien-17-one and minor amounts of the 3β-acetoxy-4α-chloro-5-ene and 3β-acetoxy-6α-chloro-4-ene." @default.
- W2950562722 created "2019-06-27" @default.
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- W2950562722 date "1988-10-04" @default.
- W2950562722 modified "2023-09-24" @default.
- W2950562722 title "ChemInform Abstract: Steroidal Allylic and Homoallylic Rearrangements During Halogenation with Triphenylphosphine and Carbon Tetrachloride." @default.
- W2950562722 cites W1984217490 @default.
- W2950562722 doi "https://doi.org/10.1002/chin.198840257" @default.
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