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• W2950566684 startingPage "1282" @default.
• W2950566684 abstract "The 12-vertex closo-phosphaborane 1,7-P2B10Cl10 (1) has been prepared in low yield from the pyrolysis reaction of B2Cl4 with PCl3 at temperatures above 400 degrees C. A single-crystal X-ray structure determination of 1 (monoclinic space group P2(1)/n with a = 9.239(2) A, b = 16.786(3) A, c = 15.739(3) a, beta = 93.25(3) degrees, and Z = 4) confirmed that, consistent with its 26 skeletal electron count, the phosphaborane adopts a distorted icosahedral structure with the phosphorus atoms in the 1,7-positions. Crystals of 1 contain toluene in a 1:1 molar ratio embedded between each P atom of neighboring cluster molecules. Alteration of the pyrolytic conditions resulted in the formation of the phosphaboranes P4B8Cl6 (2) and P2B8Cl8 (3), which were characterized spectroscopically. Copyrolysis of B2Cl4 with a mixture of PCl3 and AsCl3 at 450 degrees C generated the six-vertex arsaphosphaborane AsPB4Cl4 (4) and traces of the icosahedral arsaphosphaborane AsPB10Cl10. These compounds are examples of heteroboranes which contain two different group-15 atoms within a single molecule." @default.
• W2950566684 created "2019-06-27" @default.
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• W2950566684 date "2000-03-01" @default.
• W2950566684 modified "2023-10-12" @default.
• W2950566684 title "Synthesis of Halogenated Polyhedral Phosphaboranes. Crystal Structure of <i>closo</i>-1,7-P₂B₁₀Cl₁₀" @default.
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• W2950566684 doi "https://doi.org/10.1021/ic990112v" @default.
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