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- W2950583451 abstract "The kinetics of oxidation of cyclohexanone(chxn), 2-butanone(but), and 1,3-dihydroxy-2-propanone (dhp) have been investigated in aqueous acidic media. A first-order dependence in complex is obtained at high acid and low oxidant concentration for these ketones. However, a zero-order rate prevails at high oxidant and low acid concentration, and this rate has been shown to be acid catalyzed enolization rate of the ketone. A general rate expression has been derived to explain these behaviours and plausible mechanism has been offered by assuming the enol as the reactive species" @default.
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- W2950583451 date "1990-04-10" @default.
- W2950583451 modified "2023-09-27" @default.
- W2950583451 title "ChemInform Abstract: Kinetics and Mechanism of the Oxidation of Some Cyclic and Acyclic Ketones by Dodecatungstocobaltate(III) - A Comparative Study." @default.
- W2950583451 cites W2086199701 @default.
- W2950583451 doi "https://doi.org/10.1002/chin.199015075" @default.
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