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- W2950583862 abstract "High pressure fluorescence studies from 0–10 kbar have been performed on electron donor–acceptor (EDA) complexes of s‐tetracyanobenzene (TCNB) with a series of aromatic hydrocarbons. Four solvents were used: 2,2,4,4,6,8,8‐heptamethylnonane (HMN), methylcyclohexane (MCH), 2,6,10,14‐tetramethylpentadecane (TMPD), and a mixture of MCH and HMN. A viscosity range from 0.006 to 10 000 P was covered at two temperatures: 0 and 25 °C. As pressure (viscosity) increased the fluorescence spectrum shifted from one dominated by emission from the equilibrium (EQ) excited singlet state to one dominated by Franck–Condon (FC) singlet emission. Lifetime measurements for the complexes of o‐xylene and p‐xylene with TCNB yielded the two radiative rates (kEQ and kFC) as well as the rate of relaxation from FC to the EQ excited state (kRE). kRE was found to correlate well with viscosity and to be independent of temperature at constant viscosity, indicating that the relaxation process is diffusion controlled." @default.
- W2950583862 created "2019-06-27" @default.
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- W2950583862 date "1982-03-02" @default.
- W2950583862 modified "2023-09-24" @default.
- W2950583862 title "ChemInform Abstract: HIGH PRESSURE STUDY OF VISCOSITY AND TEMPERATURE EFFECTS ON TETRACYANOBENZENE EDA COMPLEXES" @default.
- W2950583862 cites W1981291169 @default.
- W2950583862 doi "https://doi.org/10.1002/chin.198209067" @default.
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