Matches in SemOpenAlex for { <https://semopenalex.org/work/W2950585415> ?p ?o ?g. }
Showing items 1 to 80 of
80
with 100 items per page.
- W2950585415 endingPage "88" @default.
- W2950585415 startingPage "83" @default.
- W2950585415 abstract "Abstract The preparation of non-symmetrical ketones by the reaction of acyl chlorides and the corresponding Grignard reagents in the presence of catalytic amounts of metal halides is described. The composition of catalyst has a great influence on the yield of the required ketone as well as on side product formation. For each catalytic system, the yield of ketone and the number of side products changes with the time of addition of the Grignard reagent. We examined the influence of both factors in our model reaction of adamantane-1-carbonyl chloride with ethylmagnesium bromide and discussed the possible mechanisms from this point of view. We have found ZnCl 2 , MnCl 2 , AlCl 3 and CuCl to be active catalytic components and developed very efficient, cheap and fast methods for the preparation of alkyl adamantyl ketones. The procedure was also tested for the synthesis of other alkyl aryl ketones." @default.
- W2950585415 created "2019-06-27" @default.
- W2950585415 creator A5035288212 @default.
- W2950585415 creator A5038922656 @default.
- W2950585415 date "2005-01-01" @default.
- W2950585415 modified "2023-09-24" @default.
- W2950585415 title "Influence of catalytic system composition on formation of adamantane containing ketones" @default.
- W2950585415 cites W1976555322 @default.
- W2950585415 cites W1982400720 @default.
- W2950585415 cites W1986484278 @default.
- W2950585415 cites W1994117041 @default.
- W2950585415 cites W2004741745 @default.
- W2950585415 cites W2006352465 @default.
- W2950585415 cites W2014249043 @default.
- W2950585415 cites W2015316193 @default.
- W2950585415 cites W2032351529 @default.
- W2950585415 cites W2035594073 @default.
- W2950585415 cites W2038209167 @default.
- W2950585415 cites W2058554827 @default.
- W2950585415 cites W2059204392 @default.
- W2950585415 cites W2076511248 @default.
- W2950585415 cites W2078218081 @default.
- W2950585415 cites W2080527822 @default.
- W2950585415 cites W2113645340 @default.
- W2950585415 cites W2313592619 @default.
- W2950585415 cites W2315474675 @default.
- W2950585415 cites W2321727024 @default.
- W2950585415 cites W2951224518 @default.
- W2950585415 doi "https://doi.org/10.1016/j.tet.2004.10.059" @default.
- W2950585415 hasPublicationYear "2005" @default.
- W2950585415 type Work @default.
- W2950585415 sameAs 2950585415 @default.
- W2950585415 citedByCount "16" @default.
- W2950585415 countsByYear W29505854152012 @default.
- W2950585415 countsByYear W29505854152013 @default.
- W2950585415 countsByYear W29505854152014 @default.
- W2950585415 countsByYear W29505854152017 @default.
- W2950585415 countsByYear W29505854152020 @default.
- W2950585415 countsByYear W29505854152021 @default.
- W2950585415 countsByYear W29505854152022 @default.
- W2950585415 crossrefType "journal-article" @default.
- W2950585415 hasAuthorship W2950585415A5035288212 @default.
- W2950585415 hasAuthorship W2950585415A5038922656 @default.
- W2950585415 hasConcept C138885662 @default.
- W2950585415 hasConcept C161790260 @default.
- W2950585415 hasConcept C178790620 @default.
- W2950585415 hasConcept C185592680 @default.
- W2950585415 hasConcept C21951064 @default.
- W2950585415 hasConcept C2779556047 @default.
- W2950585415 hasConcept C40231798 @default.
- W2950585415 hasConcept C41895202 @default.
- W2950585415 hasConceptScore W2950585415C138885662 @default.
- W2950585415 hasConceptScore W2950585415C161790260 @default.
- W2950585415 hasConceptScore W2950585415C178790620 @default.
- W2950585415 hasConceptScore W2950585415C185592680 @default.
- W2950585415 hasConceptScore W2950585415C21951064 @default.
- W2950585415 hasConceptScore W2950585415C2779556047 @default.
- W2950585415 hasConceptScore W2950585415C40231798 @default.
- W2950585415 hasConceptScore W2950585415C41895202 @default.
- W2950585415 hasIssue "1" @default.
- W2950585415 hasLocation W29505854151 @default.
- W2950585415 hasOpenAccess W2950585415 @default.
- W2950585415 hasPrimaryLocation W29505854151 @default.
- W2950585415 hasRelatedWork W1973047607 @default.
- W2950585415 hasRelatedWork W1993870437 @default.
- W2950585415 hasRelatedWork W2000989138 @default.
- W2950585415 hasRelatedWork W2046693525 @default.
- W2950585415 hasRelatedWork W2322262719 @default.
- W2950585415 hasRelatedWork W2323350032 @default.
- W2950585415 hasRelatedWork W2344080027 @default.
- W2950585415 hasRelatedWork W2345136663 @default.
- W2950585415 hasRelatedWork W2356832339 @default.
- W2950585415 hasRelatedWork W4252126646 @default.
- W2950585415 hasVolume "61" @default.
- W2950585415 isParatext "false" @default.
- W2950585415 isRetracted "false" @default.
- W2950585415 magId "2950585415" @default.
- W2950585415 workType "article" @default.