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- W2950586948 abstract "Low temperature reaction of [Cr(CO)5{C(Cl)MNe2}], (I), with (a) AgQ yields [Cr(CO)5(CNMe2]+Q–(Q = BF4, PF6, or ClO4), (II), (b) BCl3 gives (II, Q = BCl4), (c) PPh3 affords cis-[Cr(CO)4(PPh3){C(Cl)NMe2}], and (d) KCN gives [Cr(CO)5{C(CN)NMe2}]; the latter is also obtained from (II, Q = BF4), which additionally with LiNMe2 furnishes [Cr(CO)5{C(NMe2)2}] and with PEt3 or [Bu4N]+I– the carbyne complexes trans-[Cr(CO)4-(PEt3)(CNMe2)]+[BF4]– or trans-[Cr(CO)4I(CNMe2)]." @default.
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- W2950586948 date "1977-02-01" @default.
- W2950586948 modified "2023-09-26" @default.
- W2950586948 title "ChemInform Abstract: THE ROLE OF C-CHLOROCARBENEMETAL COMPLEXES IN CARBENE- AND CARBYNE-METAL COMPLEX CHEMISTRY, EXPERIMENTS WITH (CR(CO)5(C(CL)NME2)) AND (CR(CO)5(CNME2))+" @default.
- W2950586948 cites W2000674946 @default.
- W2950586948 doi "https://doi.org/10.1002/chin.197705286" @default.
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