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- W2950595598 abstract "The highly diastereoselective chain extension of (R)- or (S)-(R∗,R∗)-1,2-dicyclohexylethane-1,2-diol (‘DICHED’) boronic esters has been applied to enantiomerically pure DICHED [(trityloxy)methyl]boronate to provide possible precursors of kainic acid. A five carbon chain has been assembled having the two critical stereogenic centers in the correct absolute configurations, with the third stereogenic center in a single absolute configuration potentially convertible to the correct amino acid diastereomer. However, peroxidic deboronation of the potential sec-kainic acid precursor took an unexpected course." @default.
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- W2950595598 date "1997-12-01" @default.
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- W2950595598 title "Stereoselective chain extension of (R,R)- or (S,S)-1,2-dicyclohexylethane-1,2-diol trityloxymethylboronate to compounds having three stereogenic centers" @default.
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- W2950595598 doi "https://doi.org/10.1016/s0957-4166(97)00569-7" @default.
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