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- W2950595905 abstract "An efficient and practical protocol for the enantioselective cobalt-catalyzed hydrovinylation of vinylarenes with ethylene at low (1.2 bar) pressure has been developed. As precatalysts, stable [L2 CoCl2 ] complexes are employed that are activated in situ with Et2 AlCl. A modular chiral TADDOL-derived phosphine-phosphite ligand was identified that allows the conversion of a broad spectrum of substrates, including heterocyclic vinylarenes and vinylferrocene, to smoothly afford the branched products with up to 99 % ee and virtually complete regioselectivity. Even polar functional groups, such as OH, NH2 , CN, and CO2 R, are tolerated." @default.
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- W2950595905 date "2016-09-01" @default.
- W2950595905 modified "2023-09-27" @default.
- W2950595905 title "ChemInform Abstract: Low-Pressure Cobalt-Catalyzed Enantioselective Hydrovinylation of Vinylarenes." @default.
- W2950595905 cites W2304220094 @default.
- W2950595905 doi "https://doi.org/10.1002/chin.201641025" @default.
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