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- W2950596717 abstract "4-Pentenylketenes 4a and 9 and cyclopropylketenes 3a, 13, 14 (RCHCO) are generated by photochemical Wolff rearrangements and observed by IR as relatively long-lived species at room temperature in hydrocarbon solvents. The reactions of these ketenes with the nitroxyl radicals tetramethylpiperidinyloxyl (TEMPO, TO•) and tetramethylisoindoline-2-oxyl (TMIO, IO•) form carboxy substituted 5-hexenyl and cyclopropylmethyl radicals which are either trapped by a second nitroxyl radical or undergo rearrangements followed by trapping. The rate constant of the reaction of 4a with TEMPO was similar to that of n-BuCHCO (1b), while 3a was 4.3 times more reactive, indicating cyclopropyl stabilization of the incipient radical." @default.
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- W2950596717 date "2001-07-28" @default.
- W2950596717 modified "2023-09-26" @default.
- W2950596717 title "Nitroxyl Radical Reactions with 4-Pentenyl- and Cyclopropylketenes: New Routes to 5-Hexenyl- and Cyclopropylmethyl Radicals" @default.
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- W2950596717 doi "https://doi.org/10.1021/jo0102922" @default.
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