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• W2950602018 abstract "The valuable chiral sources C(9),C(10)-disubstituted camphors can be enantiospecifically obtained from the corresponding C(9)-substituted camphors by a general and straightforward synthetic method. This method involves the electrophilic treatment of a key 2-methylenenorbornan-1-ol intermediate, followed by a controlled tandem carbon-carbon double-bond addition-Wagner-Meerwein rearrangement of the norbornane framework. Discussion of the results presented suggests possible extensions and limitations of the methodology used. The feasibility of this method has been exemplified by the highly efficient enantiospecific preparation of several interesting C(9)-halogen-, C(10)-halogen, O-, S-, or Se-substituted camphors." @default.
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• W2950602018 date "2004-09-16" @default.
• W2950602018 modified "2023-10-03" @default.
• W2950602018 title "Enantiospecific Access to Various C(9),C(10)-Disubstituted Camphors: Scope and Limitations" @default.
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• W2950602018 doi "https://doi.org/10.1021/jo049462b" @default.
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