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- W2950602502 abstract "Palladium-catalyzed carbonylative cross-methylation reactions of different chloroarene-Cr(CO)3 complexes employing an intramolecularly stabilized dimethylindium (III) reagent have been studied. The coupling products (acetophenone derivatives) were isolated in 43-96% yield under standard reaction conditions (5 mol% PdCl2(PPh3)2, 50 °C, 5 atm CO-pressure in THF). Also, carbonylative Suzuki-coupling reactions of phenylboronic acid with different chloroarene-Cr(CO)3 complexes afforded the corresponding benzophenone derivatives in 48-78% yield under comparable conditions in the presence of potassium carbonate as a base." @default.
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- W2950602502 date "2002-01-01" @default.
- W2950602502 modified "2023-09-23" @default.
- W2950602502 title "Pd-Catalyzed Carbonylative Cross-coupling Reactions of Chloroarene-Cr(CO)3 Complexes" @default.
- W2950602502 doi "https://doi.org/10.1055/s-2002-32594" @default.
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