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- W2950603923 abstract "SN2‘ (γ) substitutions of δ-substituted allylic acetates with Grignard reagents and copper catalysts proceed with high diastereoselectivities. With benzyloxy, methoxymethoxy, and tert-butyldimethylsiloxy groups, reactions favor the anti-isomer with selectivities up to anti:syn = >99:1. With a hydroxyl group, selectivities are reversed and the syn-isomer is favored with selectivities up to anti:syn = <1:99." @default.
- W2950603923 created "2019-06-27" @default.
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- W2950603923 date "2002-04-05" @default.
- W2950603923 modified "2023-10-12" @default.
- W2950603923 title "Diastereoselective Reactions of δ-Oxy-Substituted Allylic Acetates with Organocopper Reagents" @default.
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- W2950603923 doi "https://doi.org/10.1021/jo016310x" @default.
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