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- W2950604105 abstract "The regioselectivity of the metal-catalyzed ring opening of unsymmetrical 1,2-dioxines to cis-γ-hydroxyenones was investigated using two different Co(II) salen complexes. Regioselectivity was determined by direct examination of the enone ratios and by derivitization with a stabilized phosphorus ylide. The steric influence of the substituents on the 1,2-dioxine was the primary influence on regioselectivity. Temperature played little role; however, solvent and selection of Co(II) complex could be used to mildly influence the outcome of the rearrangement for selected substrates. The origins of the selectivity for the reaction are discussed." @default.
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- W2950604105 date "2004-12-23" @default.
- W2950604105 modified "2023-10-18" @default.
- W2950604105 title "Ring-Opening of Unsymmetrical 1,2-Dioxines Using Cobalt(II) Salen Complexes" @default.
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- W2950604105 doi "https://doi.org/10.1021/jo040241f" @default.
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