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• W2950606194 endingPage "443" @default.
• W2950606194 startingPage "430" @default.
• W2950606194 abstract "The syntheses of 1,1‘-bis(chloromethyldimethylsilyl)ferrocene, fc(SiMe2CH2Cl)2 (2), of the series of open-chain ferrocene- and silicon-containing organotin(IV) compounds (FcMe2SiCH2)2SnPh2 (3), (FcMe2SiCH2SnXPh)2CH2 (4, X = Ph; 7, X = I; 8, X = Cl; 9, X = F), fc(SiMe2CH2SnXR2)2 (5, R = X = Ph; 6, R = X = Me; 10, R = Ph, X = I; 11, R = Me, X = Cl; 12, R = Ph, X = Cl; 13, R = Ph, X = F), fc(SiMe2CH2SnPh2CH2SiMe2Fc)2 (14), and of the ferrocenophanes [fc(SiMe2CH2SnXRCH2SiMe2)2fc] (15, R = X = Me; 16, R = X = Ph; 17, R = Ph, X = I; 18, R = Ph, X = F; 19, R = Ph, X = Cl; 20, R = Me, X = Cl) and two of their chloride complexes {[fc(SiMe2CH2SnClRCH2SiMe2)2fc·2Cl]2- 2[(Ph3P)2N]+} (22, R = Me; 23, R = Ph) are reported, and the molecular structures of 4, 16, 17, 19, 20, 22, and 23 are described. In solution, the halogen-substituted ferrocenophanes 17−19 undergo cis−trans isomerization, the rate of which is enhanced by addition of halide ions. Variable-temperature 119Sn and 19F NMR studies in solution indicate that the fluoro derivatives 9, 13, and 18 react with different molar equivalents of fluoride ions to give the 1:1 and 1:2 adducts [(FcMe2SiCH2SnFPh)2CH2·nF]n-[Bu4N]+n (9a,b, n = 1; 9c, n = 2), {[13·2F]2-[Bu4N]+2}, and {[18·F]-[Bu4N]+} and {[18·2F]2-[Bu4N]+2}, respectively. A more extended electrochemical investigation points out that the species containing halogen-substituted tin groups are more sensitive to anions than their analogues containing diphenyltin groups." @default.
• W2950606194 created "2019-06-27" @default.
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• W2950606194 date "2000-01-21" @default.
• W2950606194 modified "2023-10-09" @default.
• W2950606194 title "Novel Silicon- and Tin-Containing Ferrocenophanes and Related Compounds as Lewis Acids" @default.
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• W2950606194 doi "https://doi.org/10.1021/om9905660" @default.
• W2950606194 hasPublicationYear "2000" @default.
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