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- W2950623449 abstract "A new “formal” Ru-catalyzed [4+2+2] cycloaddition of 1,6-diynes to 1,3-dienes giving conjugated 1,3,5-cyclooctatrienes and vinylcyclohexadienes is described. This formal cycloaddition is really a tandem process, the Ru(II)-catalyzed formation of (Z)-tetraenes or vinyl-(Z)-trienes followed by a pure thermal conrotatory 8π- or disrotatory 6π-electrocyclization. The proposed mechanism allows the differences in product ratio to be explained in terms of steric and stereochemical considerations." @default.
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- W2950623449 date "2003-07-17" @default.
- W2950623449 modified "2023-10-03" @default.
- W2950623449 title "“Formal” Ruthenium-Catalyzed [4+2+2] Cycloaddition of 1,6-Diynes to 1,3-Dienes: Formation of Cyclooctatrienes vs Vinylcyclohexadienes" @default.
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- W2950623449 doi "https://doi.org/10.1021/ol0348710" @default.
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