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- W2950631609 abstract "Our recent study on oxygenation and carbon-carbon bond forming reaction of olefinic compounds using a series of cobalt (II) catalysts have been descrived in the following four reactions.(1) Catalytic hydration of olefins with molecular oxygen and 2-propanol is performed by using bis (1, 3-diketonato) cobalt complex (Oxidation-Reduction Hydration).(2) The above cobalt (II) complex efficiently promoted the novel peroxygenation of a wide range of olefinic compounds with molecular oxygen and triethylsilane to afford the triethylsilyl peroxides in high yields. (Triethylsilylperoxygenation) (3) The cross coupling reactions of α, β-unsaturated compound with aldehyde and phenylsilane proceed in the presence of the cobalt (II) catalyst to give the aldol-type product.(4) Under the similar condition, catalytic oximation of α, β-unsaturated compound is achieved by using butylnitrite as an electrophile. The synthetic applications and a possible reaction path-way are also described." @default.
- W2950631609 created "2019-06-27" @default.
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- W2950631609 date "1992-01-01" @default.
- W2950631609 modified "2023-09-30" @default.
- W2950631609 title "Development of Novel Methodology in Organic Synthesis Using Cobalt(II) Catalyst." @default.
- W2950631609 doi "https://doi.org/10.5059/yukigoseikyokaishi.50.190" @default.
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