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- W2950640319 abstract "Publisher Summary Methylcyclopentanoid monoterpenes are a group of isoprenoids characterized by the presence of a cyclopentanoid residue in their skeleton. One aspect of methylcyclopentanoid monoterpenes is their biological role for the organisms that biosynthesize them. The biogenesis of methylcyclopentanoid monoterpenes has been carefully studied allowing the key steps of the process to be depicted. Iridodial and iridotrial intermediates can arise by different biogenetic pathways, giving rise to different groups of methylcyclopentanoid monoterpenes. Secologanin is probably one of the best known secoiridoids, being the monoterpenic key intermediate in the biogenesis of indole and related alkaloids. Synthesis via bicyclononadiene derivatives has been used essentially for the total synthesis of genipin, which has been described by Buchi and which allowed the confirmation of the structure of this compound, as well as the stereochemical assignments related to it." @default.
- W2950640319 created "2019-06-27" @default.
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- W2950640319 date "2010-06-15" @default.
- W2950640319 modified "2023-09-25" @default.
- W2950640319 title "ChemInform Abstract: Stereoselective Synthesis of Methylcyclopentanoid Monoterpenes" @default.
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- W2950640319 doi "https://doi.org/10.1002/chin.199925243" @default.
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