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- W2950649862 abstract "Alkali-induced hydrolysis of fluoro-complexes of Ta and Nb affords one-pot synthesis of well crystallized compounds containing Lindqvist hexatantalate [Ta6O19]8 − and hexaniobate [Nb6O19]8 − ions. As an example, Na8Ta6O19·26H2O, a polyoxometalate with a remarkably complex layered structure was synthesized using the new method. An advantage of the proposed synthetic approach is that it can be easily embedded into existing technological flowcharts for the processing of Nb and Ta allowing direct synthesis of polyoxometalates from inexpensive fluoride precursors." @default.
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- W2950649862 date "2012-11-01" @default.
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- W2950649862 title "The fluoride route to Lindqvist clusters: Synthesis and crystal structure of layered hexatantalate Na8Ta6O19·26H2O" @default.
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- W2950649862 doi "https://doi.org/10.1016/j.inoche.2012.08.025" @default.
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