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- W2950650118 abstract "Abstract Broussonetone A (1) and broussonetone B (2), two novel dimeric abietane diterpenes, have been isolated from Salvia broussonetii root cultures transformed by Agrobacterium rhizogenes. The structure of broussonetone A was determined from spectroscopic data and confirmed by X-ray analysis. This dimer can be formed by a [4+2]-cycloaddition of two molecules of 13β-hydroxyabieta-8(14),9(11)-dien-12-one. NMR data of broussonetone B indicated that the C-20 methyl in part B of the broussonetone A molecule had been substituted by an aldehyde group. Thus, broussonetone B could be formed by an analogous Diels Alder reaction between 13β-hydroxyabieta-8(14),9(11)-dien-12-one as the dienophile and its 20-oxo derivative as the electrophile." @default.
- W2950650118 created "2019-06-27" @default.
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- W2950650118 date "2014-01-01" @default.
- W2950650118 modified "2023-10-12" @default.
- W2950650118 title "Two novel abietane dimers from transformed root cultures of Salvia broussonetii" @default.
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- W2950650118 doi "https://doi.org/10.1016/j.tetlet.2013.12.031" @default.
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