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- W2950651485 abstract "Degradation of (—)-laudanosine, a 1-benzyl-1,2,3,4-tetrahydroisoquinoline alkaloid, with ethyl chloroformate (ECF) affordedan optically active chloro-carbamate as an intermediate. The reason why this intermediate exhibits an opticalactivity was investigated by comparison with the reactions of some model compounds with ECF. It may be supposedthat the chloride group in a hypothetic carbenium ion intermediate stands very closely to the chiral center, so conservingoptical activity. However, a neighboring group effect can not be excluded." @default.
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- W2950651485 date "1991-01-01" @default.
- W2950651485 modified "2023-09-26" @default.
- W2950651485 title "Optically Active Intermediate from Degradation of (-)-Laudanosine, a Benzylisoquinoline Alkaloid, with Ethyl Chloroformate" @default.
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