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- W2950653891 abstract "Abstract The total synthesis of the norsesquiterpene 7‐demethyl‐2‐methoxycalamenene ( 1 ) by a newly developed enantioselective silane‐terminated Heck reaction is described. The Pd 0 ‐catalyzed transformation of the allylsilane 7 , obtained from 3‐(3‐methoxyphenyl)propanol ( 2 ) in 7 steps, provides the tetralin 8 in 91% yield and with 92% ee in the presence of ( R )‐BINAP. Transformation of 8 via 14 and 15 gives 1 . The absolute configuration of 1 which has previously not been known was deduced from a single‐crystal X‐ray analysis of 10 , obtained from the cyclization product 8 by hydroboration and acylation with camphanic acid chloride." @default.
- W2950653891 created "2019-06-27" @default.
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- W2950653891 date "1996-12-01" @default.
- W2950653891 modified "2023-10-12" @default.
- W2950653891 title "Enantioselective Total Synthesis and Absolute Configuration of the Natural Norsesquiterpene 7‐Demethyl‐2‐methoxycalamenene by a Silane‐Terminated Intramolecular Heck Reaction" @default.
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- W2950653891 doi "https://doi.org/10.1002/jlac.199619961207" @default.
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