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- W2950657617 abstract "The first compounds, Hg7Ag2P8X6 (X = Br, I) and Hg6Ag4P8Br6, featuring the partial isoelectronic substitution of Hg2+ for Ag1+ in mercury−pnicogen frameworks have been obtained and structurally characterized. The new compounds are the supramolecular assemblies built of the covalently bonded metal−pnicogen frameworks trapping guests of different complexity. The frameworks feature the perfect ordering of Hg2+ and Ag1+ cations and contain P24- and P66- phosphorus clusters. The substitution of Hg2+ with Ag1+ leads to the reduction in charge of the host cluster-containing cationic matrix and concomitant replacement of the monatomic X- guest by a lesser amount of the AgBr32- anions." @default.
- W2950657617 created "2019-06-27" @default.
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- W2950657617 date "2006-03-14" @default.
- W2950657617 modified "2023-09-23" @default.
- W2950657617 title "Reduction of the Host Cationic Framework Charge by Isoelectronic Substitution: Synthesis and Structure of Hg7Ag2P8X6 (X: Br, I) and Hg6Ag4P8Br6." @default.
- W2950657617 cites W1966270924 @default.
- W2950657617 doi "https://doi.org/10.1002/chin.200611024" @default.
- W2950657617 hasPublicationYear "2006" @default.
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