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• W2950658532 startingPage "2045" @default.
• W2950658532 abstract "The influence of the partial substitution of Sr by Ba in the SrCoO3−y on its structure and properties has been investigated. SrBaCo2O5 is stable at room temperature as a cubic phase with a high oxygen vacancy concentration. This structure is stable up to 800 K. Above this temperature, the phase decomposes into a monodimensional rhombohedral (SrBa)7Co6O18 phase. At 1200 K, a reversible rhombohedral → cubic transformation is observed, the rhombohedral phase remaining stable until room temperature. SrBaCo2O5 shows antiferromagnetic behavior with TN ≈ 525 K. As determined by neutron diffraction data, the magnetic Co spins align ferromagnetically on the (111) planes and these planes are stacked antiferromagnetically in the normal direction (type II antiferromagnet). The temperature dependence of the electrical conductivity indicates SrBaCo2O5 to be a semiconducting p-type material with an activation energy of ∼0.3 eV." @default.
• W2950658532 created "2019-06-27" @default.
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• W2950658532 date "2009-04-30" @default.
• W2950658532 modified "2023-10-02" @default.
• W2950658532 title "Synthesis, Structural, Magnetic, and Electrical Study of BaSrCo₂O₅, a Highly Disordered Cubic Perovskite" @default.
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• W2950658532 doi "https://doi.org/10.1021/cm802606s" @default.
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