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- W2950658959 abstract "The lowering of Cβ–H stretching frequencies in carbocations 1a–d and 2a–c induced by hyperconjugation was tested as a possible probe for estimating the electron donating ability of α-substituents. Conclusions are based on the results of high level quantum chemical calculations confirmed with experimental FT-IR spectra. Because the decrease in the Cβ–H stretching frequency is comparable in 1b and in 1c, and in 2b and 2c respectively, it follows that α-substitution by a methyl group or by chlorine stabilizes a carbocation with almost the same effectiveness." @default.
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- W2950658959 date "2010-06-17" @default.
- W2950658959 modified "2023-10-05" @default.
- W2950658959 title "ChemInform Abstract: C-H Hyperconjugation in α-Chlorocarbocations." @default.
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- W2950658959 doi "https://doi.org/10.1002/chin.199909057" @default.
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