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- W2950664077 abstract "The reaction of 4-R-substituted styrenes (R = H, Me, Cl, CF3, NO2) with N2O5 in dichloromethane gives several products including 1-aryl-2-mtroethyl nitrate 1,1,2-dinitro-1-arylethane 2,1,2-dinitrato-1-arylethane 3 and 2-aryl-2-nitroethyl nitrate 4. When R = CF3 or NO2, 1–4 are the only products and 1 predominates at low temperature and/or high concentrations of N2O5. All are formed in part by radical pathways, as is shown by 15N CIDNP effects. Evidence for ionic pathways is also presented. The kinetics of formation of 1 from 4-nitrostyrene at –45 °C are of high order in N2O5." @default.
- W2950664077 created "2019-06-27" @default.
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- W2950664077 date "2010-08-04" @default.
- W2950664077 modified "2023-09-26" @default.
- W2950664077 title "ChemInform Abstract: Nitration of Styrenes by Dinitrogen Pentoxide in Dichloromethane." @default.
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- W2950664077 doi "https://doi.org/10.1002/chin.199640084" @default.
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