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- W2950664513 abstract "Optically active imidazole derivatives featuring an α-amino acid motif substituted at the 2-position can be prepared in moderate to good yields by Negishi as well as Suzuki-Miyaura cross-couplings as the key synthetic steps. The reaction sequence involves N-protection (ethoxymethylation), whereby both generated regioisomers could be separated by column chromatography, and selective 2-lithiation. Subsequent transmetalation to zinc or an iodine quench affords reactants suitable for Pd-catalyzed Negishi and Suzuki-Miyaura reactions with (hetero)aromatics." @default.
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- W2950664513 date "2008-12-12" @default.
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- W2950664513 title "Design and Efficient Synthesis of Amino Acid Derived 2-Substituted Imidazoles by Palladium-Catalyzed Cross-Coupling Reactions" @default.
- W2950664513 doi "https://doi.org/10.1055/s-0028-1083263" @default.
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