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- W2950668812 abstract "The structures of the new compound La(1.2)Sr(2.7)IrO(7.33) and the recently discovered La(1.2)Sr(2.7)RuO(7.33) have been solved using a combination of X-ray and neutron diffraction. Both compounds crystallize in the trigonal space group Rm and consist of isolated MO6 (M = Ru, Ir) octahedra, which are arranged in well-defined hexagonal perovskite slabs. These slabs are separated by (Sr2O(1+delta)) layers containing both O2- and (O2)2- ions. The composition can therefore be written as La(1.2)Sr(2.7)MO(7-delta)(O2)delta with delta = 0.33. Results of the magnetic susceptibility and XANES measurements show that the transition metal cations are in a pentavalent state. While in La(1.2)Sr(2.7)RuO(7.33) an antiferromagnetic interaction between the Ru5+ ions is found, La(1.2)Sr(2.7)IrO(7.33) shows a very small temperature-independent paramagnetism down to 1.8 K due to the strong spin-orbit coupling characteristic for the 5d element iridium." @default.
- W2950668812 created "2019-06-27" @default.
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- W2950668812 date "2005-09-01" @default.
- W2950668812 modified "2023-10-04" @default.
- W2950668812 title "Structural and Magnetic Properties of Hexagonal Perovskites La1.2Sr2.7MO7.33(M = Ru, Ir) Containing Peroxide Ions" @default.
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- W2950668812 doi "https://doi.org/10.1021/ic050511s" @default.
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