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- W2950680919 abstract "Abstract The 1,3-addition of methylmagnesium chloride to dialdose derived nitrones 3 and 7 afforded N- benzylhydroxylamines 4 5 and 8 9 , respectively, in high yields. The stereoselectivity of the addition reaction was improved by the use of trimethylsilyl triflate. The NO bond reductive cleavages of N-benzylhydroxylamines took place in good yields and offered an easy access to N-benzylaminosugars. The potential of these aminosugars is demonstrated by the synthesis of glycosidase inhibitor 6-deoxynojirimycin 1a." @default.
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- W2950680919 date "2010-08-03" @default.
- W2950680919 modified "2023-09-30" @default.
- W2950680919 title "ChemInform Abstract: A New Route to Aminosugars from Sugar Nitrones: Synthesis of 6- Deoxynojirimycin." @default.
- W2950680919 cites W2167039819 @default.
- W2950680919 doi "https://doi.org/10.1002/chin.199739241" @default.
- W2950680919 hasPublicationYear "2010" @default.
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