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- W2950682314 abstract "The Lewis acid mediated intramolecular additions of allylsilanes to acetal substrates are described. Excellent regio- and diastereoselectivity are achieved by boron trifluoride promoted cyclization of allysilane-acetals 5 and 8 derived from hydroxy allysilances 3. Cyclizations occur in moderate to high yields, providing directr routes to cis-2, 6-disubstituted 4-methylenetetrahydropyrans 6 and 9." @default.
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- W2950682314 date "1998-01-01" @default.
- W2950682314 modified "2023-09-26" @default.
- W2950682314 title "Stereocontrolled Preparation of 2,6-Disubstituted 4-Methylenetetrahydropyrans by Lewis Acid Promoted Allylsilane-Acetal Cyclization" @default.
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