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• W2950686688 endingPage "2080" @default.
• W2950686688 startingPage "2065" @default.
• W2950686688 abstract "It has been known that the enantioselectivity of the chiral Lewis base-catalyzed, SiCl4-promoted kinetic resolution of α,β-dichloro cis-vinyl epoxide is highly influenced by the configuration of the distal β-chlorine-bearing stereocenter. In this report, the precise nature of this unusual remote stereocontrol was investigated both experimentally and theoretically. Upon examination of a substrate that has an alkyl group in place of the β-chlorine substituent, the spatial location of major catalyst-substrate interaction was determined. Subsequently, through computational analysis of transition states, the steric repulsion by the β-substituents as well as the additional C–H/π hydrogen bond by the alkyl substituent were proposed as the crucial stereo-determining factors." @default.
• W2950686688 created "2019-06-27" @default.
• W2950686688 creator A5028165916 @default.
• W2950686688 creator A5035977092 @default.
• W2950686688 creator A5080036826 @default.
• W2950686688 date "2014-03-01" @default.
• W2950686688 modified "2023-10-07" @default.
• W2950686688 title "Organic reactions mediated by tetrachlorosilane" @default.
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