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- W2950698539 abstract "Abstract A new polymorph of Bi 2 (SO 4 ) 3 was prepared by reaction of LiBiO 2 with H 2 SO 4 and its crystal structure was solved from X-ray powder diffraction. This new polymorph crystallizes in C 2/ c space group with lattice parameters a = 17.3383(3) A, b = 6.77803(12) A, c = 8.30978(13) A, β = 101.4300(12)°. Bi 2 (SO 4 ) 3 presents a layered structure made of SO 4 sulfate groups and signs of stereochemically active Bi 3+ lone pairs. The new Bi 2 (SO 4 ) 3 absorbs water to form Bi 2 (H 2 O) 2 (SO 4 ) 2 (OH) 2 through an intermediate Bi 2 O(OH) 2 SO 4 phase, and the transition is reversible when heated under vacuum." @default.
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- W2950698539 date "2014-12-01" @default.
- W2950698539 modified "2023-10-06" @default.
- W2950698539 title "Polymorphism in Bi2(SO4)3" @default.
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- W2950698539 doi "https://doi.org/10.1016/j.solidstatesciences.2014.09.008" @default.
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