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- W2950705574 abstract "Metal-catalyzed annulation reactions to synthesize carbo- and heterocycles have been an attractive field of research for many years. The development of new cyclization reactions utilizing readily available less expensive metal catalyst is one of the important tasks. In this regard, this review summerizes and discusses about nickel- and cobalt-catalyzed [4+2] and [3+2] annulation reactions of ortho-halo substituted imines and alkynes. Nickel complexes under suitable reaction conditions underwent [4+2] annulation to form six-membered isoquinoline (salts) derivatives. However, cobalt complexes afforded aminoindenes via [3+2] annulation reactions. Both reactions proceed through a five membered metallacycle. The regioselective insertion of alkyne containing keto or ester groups into the metallacycle further demonstrates the difference in selectivity of these metal complexes." @default.
- W2950705574 created "2019-06-27" @default.
- W2950705574 creator A5049811778 @default.
- W2950705574 creator A5069900066 @default.
- W2950705574 date "2014-05-08" @default.
- W2950705574 modified "2023-09-27" @default.
- W2950705574 title "ChemInform Abstract: [4 + 2] vs [3 + 2] Annulations in the Nickel- and Cobalt-Catalyzed Reaction of ortho-Haloimines with Alkynes: Differential Reactivity Towards the Synthesis of Isoquinolines and Aminoindenes" @default.
- W2950705574 cites W2015945873 @default.
- W2950705574 doi "https://doi.org/10.1002/chin.201421250" @default.
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