Matches in SemOpenAlex for { <https://semopenalex.org/work/W2950711019> ?p ?o ?g. }
- W2950711019 endingPage "647" @default.
- W2950711019 startingPage "639" @default.
- W2950711019 abstract "Abstract The primary chemical reactions of singlet molecular oxygen with polyunsaturated carotenoids are the focus of this research report. Model compounds that exhibit electronic properties and substituent pattern similar to natural carotenes, xanthophylls or apocarotenoids, respectively, were investigated with regard to photooxygenation reactivity. For dienes and trienes as substrates, high tandem reactivity was observed and hydroperoxy-endoperoxides were isolated as the secondary products of singlet oxygen reaction. The electronic gem-effect on the regioselectivity of the ene reaction is conserved also in vinylogous positions and thus appears to originate from a radical-stabilizing effect. In an attempt to combine different peroxide groups derived from natural products as a tool for new pharmaceutically active products, a dyade synthesis of an artemisinine-safranol with subsequent singlet oxygen addition was realized." @default.
- W2950711019 created "2019-06-27" @default.
- W2950711019 creator A5013160446 @default.
- W2950711019 creator A5019381901 @default.
- W2950711019 creator A5031512034 @default.
- W2950711019 creator A5032745229 @default.
- W2950711019 creator A5039166426 @default.
- W2950711019 creator A5041823102 @default.
- W2950711019 date "2015-07-01" @default.
- W2950711019 modified "2023-09-25" @default.
- W2950711019 title "Singlet oxygen and natural substrates: functional polyunsaturated models for the photooxidative degradation of carotenoids" @default.
- W2950711019 cites W1568523187 @default.
- W2950711019 cites W1606626080 @default.
- W2950711019 cites W1838092288 @default.
- W2950711019 cites W1965142163 @default.
- W2950711019 cites W1966580306 @default.
- W2950711019 cites W1968130919 @default.
- W2950711019 cites W1968577485 @default.
- W2950711019 cites W1973325200 @default.
- W2950711019 cites W1973963845 @default.
- W2950711019 cites W1978317836 @default.
- W2950711019 cites W1983011904 @default.
- W2950711019 cites W1985145357 @default.
- W2950711019 cites W1985473988 @default.
- W2950711019 cites W1986303437 @default.
- W2950711019 cites W1987521918 @default.
- W2950711019 cites W1987986536 @default.
- W2950711019 cites W1988765421 @default.
- W2950711019 cites W1997281854 @default.
- W2950711019 cites W2011276842 @default.
- W2950711019 cites W2014387796 @default.
- W2950711019 cites W2015981461 @default.
- W2950711019 cites W2017398861 @default.
- W2950711019 cites W2019196186 @default.
- W2950711019 cites W2024273661 @default.
- W2950711019 cites W2034347671 @default.
- W2950711019 cites W2036984204 @default.
- W2950711019 cites W2039118977 @default.
- W2950711019 cites W2041615530 @default.
- W2950711019 cites W2043066472 @default.
- W2950711019 cites W2044286584 @default.
- W2950711019 cites W2045242694 @default.
- W2950711019 cites W2045543564 @default.
- W2950711019 cites W2048057581 @default.
- W2950711019 cites W2049042468 @default.
- W2950711019 cites W2062519842 @default.
- W2950711019 cites W2065527746 @default.
- W2950711019 cites W2072274768 @default.
- W2950711019 cites W2076649311 @default.
- W2950711019 cites W2079023122 @default.
- W2950711019 cites W2085170782 @default.
- W2950711019 cites W2088327041 @default.
- W2950711019 cites W2089902997 @default.
- W2950711019 cites W2090403423 @default.
- W2950711019 cites W2091592645 @default.
- W2950711019 cites W2092667345 @default.
- W2950711019 cites W2095040040 @default.
- W2950711019 cites W2100084422 @default.
- W2950711019 cites W2113140563 @default.
- W2950711019 cites W2119460565 @default.
- W2950711019 cites W2125015353 @default.
- W2950711019 cites W2127393068 @default.
- W2950711019 cites W2143579002 @default.
- W2950711019 cites W2149484475 @default.
- W2950711019 cites W2154072800 @default.
- W2950711019 cites W2317067351 @default.
- W2950711019 cites W2323692050 @default.
- W2950711019 cites W2335214266 @default.
- W2950711019 cites W2747547511 @default.
- W2950711019 cites W2949818445 @default.
- W2950711019 cites W2950890992 @default.
- W2950711019 cites W2951308181 @default.
- W2950711019 cites W4235067832 @default.
- W2950711019 doi "https://doi.org/10.1515/pac-2015-0209" @default.
- W2950711019 hasPublicationYear "2015" @default.
- W2950711019 type Work @default.
- W2950711019 sameAs 2950711019 @default.
- W2950711019 citedByCount "7" @default.
- W2950711019 countsByYear W29507110192016 @default.
- W2950711019 countsByYear W29507110192020 @default.
- W2950711019 countsByYear W29507110192021 @default.
- W2950711019 countsByYear W29507110192023 @default.
- W2950711019 crossrefType "journal-article" @default.
- W2950711019 hasAuthorship W2950711019A5013160446 @default.
- W2950711019 hasAuthorship W2950711019A5019381901 @default.
- W2950711019 hasAuthorship W2950711019A5031512034 @default.
- W2950711019 hasAuthorship W2950711019A5032745229 @default.
- W2950711019 hasAuthorship W2950711019A5039166426 @default.
- W2950711019 hasAuthorship W2950711019A5041823102 @default.
- W2950711019 hasBestOaLocation W29507110191 @default.
- W2950711019 hasConcept C121332964 @default.
- W2950711019 hasConcept C142724271 @default.
- W2950711019 hasConcept C161790260 @default.
- W2950711019 hasConcept C178790620 @default.
- W2950711019 hasConcept C181500209 @default.
- W2950711019 hasConcept C185544564 @default.
- W2950711019 hasConcept C185592680 @default.
- W2950711019 hasConcept C204787440 @default.