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- W2950711582 abstract "A series of bis(oxo/thioxothiazolinyl) aromatic atropisomers with two chiral C(aryl)-N(heterocycle) axes was synthesized. The separation of antiparallel, parallel diastereomers was achieved by chromatography on silica. Conformational assignment for the bis-thione atropisomers 1a,b-4a,b and bis-one atropisomers 9a,b-12a,b was based on polarimetric results in analytical chiral chromatography on microcrystalline cellulose triacetate. The relationship conformation-1H NMR chemical shifts, found for the bis-thiones and bis-ones was successfully applied for the conformational assignment of thione-one atropisomers not assigned by chiral liquid chromatography." @default.
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- W2950711582 date "2010-06-08" @default.
- W2950711582 modified "2023-09-28" @default.
- W2950711582 title "ChemInform Abstract: Bis[oxo/thioxothiazolinyl] Aromatic Compounds - Synthesis and Conformational Assignment." @default.
- W2950711582 cites W2022244487 @default.
- W2950711582 doi "https://doi.org/10.1002/chin.200022109" @default.
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