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- W2950715024 abstract "A simple convergent and general method has been developed for the synthesis of (±)-isopisiferin (1c), a rearranged abietane diterpene, having a hexahydrodibenzo [a,d] cycloheptene ring system, and the related model systems (1a) and (1b), through the respective enolisable tricyclic ketone mixtures (12c) and (13c), (12a) and (13a), and (12b) and (13b), obtained from the corresponding easily accessible 2-arylethyl-3,3-dimethylcyclohexanones (7c), (7a), and (7b). Demethylation of the styrenoid ethers (15b) and (15c) under acid conditions gave the tetracyclic dienones (17b) and (17c) through Ar1-5 cyclisation." @default.
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- W2950715024 date "1990-08-28" @default.
- W2950715024 modified "2023-09-28" @default.
- W2950715024 title "ChemInform Abstract: Synthetic Studies Towards Complex Diterpenoids. Part 18. Total Synthesis of (.+-.)-Isopisiferin and the Related Compounds." @default.
- W2950715024 cites W2003436720 @default.
- W2950715024 doi "https://doi.org/10.1002/chin.199035263" @default.
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