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• W2950728181 abstract "Highly substituted indole derivatives bearing alkyl and aryl moieties can be prepared by Sc(OTf)3-catalyzed Friedel–Crafts alkenylation of 5-(arylamino)pent-3-yn-2-ones. In addition, a method for regioselective hydrochlorination of 5-(arylamino)pent-3-yn-2-ones mediated by SnCl4 in moderate to good yields (up to 84%) has been developed. The resulting exclusive Z-selectivity of the C–Cl bond can be further exploited using cross C–N coupling reactions." @default.
• W2950728181 created "2019-06-27" @default.
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• W2950728181 date "2011-09-16" @default.
• W2950728181 modified "2023-10-16" @default.
• W2950728181 title "Sc(OTf)₃-Catalyzed Synthesis of Indoles and SnCl₄-Mediated Regioselective Hydrochlorination of 5-(Arylamino)pent-3-yn-2-ones" @default.
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• W2950728181 doi "https://doi.org/10.1021/jo201514q" @default.
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