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- W2950728703 abstract "Abstract Fe(Cp) 2 BF 4 is an efficient catalyst for the alcoholysis of aromatic, aliphatic, and cyclic epoxides giving excellent yields of the corresponding β-alkoxy alcohols under ambient conditions. The methanolysis of styrene oxide using Fe(Cp) 2 BF 4 as a catalyst (5 mol %) gave excellent yield of 2-methoxy-2-phenylethanol with complete regio-selectivity. The ring opening of cyclic epoxides gave 77–97% yields of trans -β-methoxy alcohols, in 0.5–6 h. The use of 1,2-epoxyhexane and 1,2-epoxydodecane as substrates gave both regioisomers in excellent yields. The first order rate of reaction with respect to catalyst was observed for the kinetics of ring opening of 1,2-epoxyhexane with methanol." @default.
- W2950728703 created "2019-06-27" @default.
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- W2950728703 date "2015-01-01" @default.
- W2950728703 modified "2023-09-27" @default.
- W2950728703 title "ChemInform Abstract: Ring Opening of Epoxides with Alcohols Using Fe(Cp)2BF4as Catalyst." @default.
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- W2950728703 doi "https://doi.org/10.1002/chin.201501031" @default.
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