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- W2950729462 abstract "Aryl radicals bearing an aldimino functional group as part of an ortho substituent cyclized by addition to C and/or N of the imino group. When the choice was between 5-exo closure to C and 6-endo closure to N, the former predominated. However, 6-endo closure to C predominated over 5-exo cyclization to N in isomeric imines. Absolute values of cyclization rate constants were determined and an explanation for the unusual 6-endo preference is offered. Chiral induction in 6-endo cyclization to C of an aldimine from D-glyceraldehyde acetonide was observed, and its sense was determined." @default.
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- W2950729462 date "1995-01-01" @default.
- W2950729462 modified "2023-09-25" @default.
- W2950729462 title "Free-Radical Chemistry of Imines" @default.
- W2950729462 doi "https://doi.org/10.1071/ch9950291" @default.
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